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Complementary halogen and hydrogen bonding: sulfur⋯iodine interactions and thioamide ribbons
Journal article

Complementary halogen and hydrogen bonding: sulfur⋯iodine interactions and thioamide ribbons

Hadi D Arman, Rebecca L Gieseking, Timothy W Hanks and William T Pennington
Chemical communications (Cambridge, England), Vol.46(11), pp.1854-1856
03/01/2010
PMID: 20198231

Abstract

Complementary halogen bonding and hydrogen bonding coexist in co-crystals of organoiodines with molecules containing the thioamide functionality. Thiourea·organoiodine co-crystals are shown to exhibit a remarkably reliable synthon with complementary N–H⋯S ribbons and S⋯I interactions.

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