Asymmetric Organocatalysis

Allan J. B Watson; David W. C Macmillan; Yi Wang; Li Deng; Seiji Shirakawa; Keiji Maruoka

doi:10.1002/9780470584248.ch2

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Book chapter

Asymmetric Organocatalysis

Allan J. B Watson, David W. C Macmillan, Yi Wang, Li Deng, Seiji Shirakawa and Keiji Maruoka

Catalytic Asymmetric Synthesis, pp.37-117

John Wiley & Sons, Inc

02/10/2010

DOI: https://doi.org/10.1002/9780470584248.ch2

Abstract

asymmetric organocatalysis ‐ enantioselective organocatalysis and iminium, enamine, somo and photoredox activation

asymmetric acid–base bifunctional organocatalysis ‐ for electrophiles and nucleophiles

enamine‐catalyzed aldehyde–aldehyde Mannich reaction

This chapter contains sections titled: Introduction Iminium‐Based Catalysis [1,2] Enamine Catalysis [1,9] New Developments in Organocatalysis References Introduction Highly Enantioselective Acid and Base Catalysis by Monofunctional Organic Catalysts Acid‐Base Bifunctional Catalysis by Small Chiral Organic Molecules Control of Enantioselectivity and Diastereoselectivity in Asymmetric Transformations with Acid‐Base Bifunctional Organic Catalysts Emerging Acid‐Base Bifunctional Chiral Organic Catalysts Conclusion and Outlook Acknowledgments References Introduction Pioneering Work Alkylation Michael Addition Aldol and Mannich Reactions Epoxidation and Aziridination Strecker Reaction Amination Ion Pair Catalysts

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Title: Asymmetric Organocatalysis
Creators: Allan J. B Watson - Department of Chemistry, Frick Laboratory, Princeton University, Washington Road, Princeton, NJ 08544, USA
David W. C Macmillan - Department of Chemistry, Frick Laboratory, Princeton University, Washington Road, Princeton, NJ 08544, USA
Yi Wang - Department of Chemistry, Brandeis University, 415 South Street, Waltham, MA 02454‐9110, USA
Li Deng - Department of Chemistry, Brandeis University, 415 South Street, Waltham, MA 02454‐9110, USA
Seiji Shirakawa - Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo‐ku, Kyoto 606‐8502, Japan
Keiji Maruoka - Department of Chemistry, Faculty of Science, Graduate School, Kyoto University, Sakyo‐ku, Kyoto 606‐8502, Japan
Contributors: Iwao Ojima (Editor) - Department of Chemistry, Stony Brook University, Stony Brook, NY 11794, USA
Publication Details: Catalytic Asymmetric Synthesis, pp.37-117
Publisher: John Wiley & Sons, Inc; Hoboken, NJ, USA
Number of pages: 79
Identifiers: 9923972821001921
Academic Unit: Department of Chemistry
Language: English
Resource Type: Book chapter

Asymmetric Organocatalysis

Abstract

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