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A Short Asymmetric Route to the Bromophycolide A and D Skeleton
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A Short Asymmetric Route to the Bromophycolide A and D Skeleton

Hongkun Lin, Susan S Pochapsky and Isaac J Krauss
Figshare
01/01/2016

Abstract

Biochemistry Biophysics Biotechnology Bromophycolide bromophycolide D ring system cyclization D SkeletonAn Ecology geranylgeranylated benzoate macrocyclic Microbiology Physiology Short Asymmetric Route synthesis transannular
An asymmetric synthesis of the bromophycolide D ring system has been achieved in seven steps from a known geranylgeranylated benzoate, via bromonium-promoted transannular cyclization of a macrocyclic intermediate.

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