Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center

Remle Çelenligil-Çetin; Lori A Watson; Chengyun Guo; Bruce M Foxman; Oleg V Ozerov

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Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center

Remle Çelenligil-Çetin, Lori A Watson, Chengyun Guo, Bruce M Foxman and Oleg V Ozerov

Figshare

01/01/2016

Abstract

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pincer bis

Ru center ligated

A Ru center ligated by a pincer bis(o-phosphinoaryl)amine (PNP) ligand in (PNP)RuH(H2) is sufficiently electron rich to break C−O and C−C bonds, resulting in the ultimate decarbonylation of hydrocarbonate and acetone, respectively, to give (PNP)RuH(CO). The decarbonylation of acetone is accompanied by hydrogenolysis of the C−C bonds to produce methane.

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Title: Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center
Creators: Remle Çelenligil-Çetin
Lori A Watson
Chengyun Guo
Bruce M Foxman
Oleg V Ozerov
Publisher: Figshare
Identifiers: 9924086747101921
Academic Unit: Department of Chemistry
Language: English
Resource Type: Dataset

Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center

Abstract

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