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(1,4,7,10,13‐Penta­methyl‐1,4,7,10,13‐penta­aza­cyclo­penta­decane‐κ5N)­cobalt(II) perchlorate
Journal article   Peer reviewed

(1,4,7,10,13‐Penta­methyl‐1,4,7,10,13‐penta­aza­cyclo­penta­decane‐κ5N)­cobalt(II) perchlorate

Feng Zhang, Jian‐Rong Zhang, Dao‐Li Deng and Ronald Hage
Acta crystallographica. Section E, Structure reports online, Vol.59(12), pp.m1099-m1101
12/2003
DOI: https://doi.org/10.1107/S1600536803025030

Abstract

The title compound, [Co(C15H35N5)](ClO4)2, conventionally abbreviated [Co(Me5PACP)](ClO4)2, where Me5PACP is 1,4,7,10,13‐penta­methyl‐1,4,7,10,13‐penta­aza­cyclo­penta­dec­ane, displays a significantly distorted trigonal–bipyramidal coordination geometry. The bond lengths and distances are comparable to those previously reported for cobalt(II) complexes with macrocyclic poly­amine ligands. The N—Co—N angle for the axial sites is 160.4 (2)°. The perchlorate anions are not coordinated.

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