A mechanism for dynamical behavior in the Landolt reaction with ferrocyanide

E. C Edblom; L Gyorgyi; M Orban; I. R Epstein

doi:10.1021/ja00250a020

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A mechanism for dynamical behavior in the Landolt reaction with ferrocyanide

Journal article

Peer reviewed

A mechanism for dynamical behavior in the Landolt reaction with ferrocyanide

E. C Edblom, L Gyorgyi, M Orban and I. R Epstein

Journal of the American Chemical Society, Vol.109(16), pp.4876-4880

1987

DOI: https://doi.org/10.1021/ja00250a020

Abstract

Catalysis

Catalysts: preparations and properties

Chemical Reactions

Computer Simulation or Modeling

Dynamical Systems

Oscillations

A mechanism consisting of 13 elementary steps is proposed for the reaction of iodate, sulfite, and ferrocyanide. Computer simulations with the mechanism give excellent agreement with experimental observations of the batch behavior of both the component Landolt (iodate-sulfite) and the full system and with the bistability and oscillation found with the full system in a stirred tank reactor.

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Title: A mechanism for dynamical behavior in the Landolt reaction with ferrocyanide; Systematic Design of Chemical Oscillators .41. A Mechanism for Dynamic Behavior in the Landolt Reaction with Ferrocyanide
Creators: E. C Edblom (Author) - Brandeis univ., dep. chemistry, Waltham MA 02254, United States
L Gyorgyi (Author) - Brandeis univ., dep. chemistry, Waltham MA 02254, United States
M Orban (Author) - Brandeis univ., dep. chemistry, Waltham MA 02254, United States
I. R Epstein (Author) - Brandeis University, Department of Chemistry
Publication Details: Journal of the American Chemical Society, Vol.109(16), pp.4876-4880
Publisher: American Chemical Society
Identifiers: 9924131325101921
Academic Unit: Benjamin and Mae Volen National Center for Complex Systems; Department of Chemistry; Interdepartmental Program in Neuroscience
Language: English
Resource Type: Journal article

A mechanism for dynamical behavior in the Landolt reaction with ferrocyanide

Abstract

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