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A new iodate oscillator: the Landolt reaction with ferrocyanide in a CSTR
Journal article

A new iodate oscillator: the Landolt reaction with ferrocyanide in a CSTR

Elizabeth C Edblom, Miklos Orban and Irving R Epstein
Journal of the American Chemical Society, Vol.108(11), pp.2826-2830
05/01/1986

Abstract

oscillator iodate
At a temperature of 30°C or higher,the reaction of sulfite, iodate,and ferrocyanide exhibits sustained oscillation in a CSTR.The system maybe thought of as a FefCN)^ perturbation of the bistable Landolt(S032~-I03~)reaction in which the ferrocyanide serves to consume the I2produced in the reduction of iodate, thereby“resettingtheclock".There action maybe monitored with pH,redoxoriodide-selective electrodes, or spectrophotometric measurement of iodine,ferrocyanide, or ferricyanide.

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