Abstract
An asymmetric synthesis of the bromophycolide D ring system has been achieved in seven steps from a known geranylgeranylated benzoate, via bromonium-promoted transannular cyclization of a macrocyclic intermediate.
- Title
- A short asymmetric route to the bromophycolide A and D skeleton
- Creators
- Hongkun Lin - Department of Chemistry, Brandeis University, Waltham, Massachusetts 02454-9110, USASusan S PochapskyIsaac J Krauss
- Publication Details
- Organic letters, Vol.13(5), pp.1222-1225
- Publisher
- United States
- Grant note
- 1S10RR017269-01 / NCRR NIH HHS S10 RR017269-01 / NCRR NIH HHS S10 RR017269 / NCRR NIH HHS
- Identifiers
- 9923957811701921
- Copyright
- © 2011 American Chemical Society
- Academic Unit
- Department of Chemistry
- Language
- English
- Resource Type
- Journal article