Activation of CO2 by a heterobimetallic Zr/Co complex

Jeremy P Krogman; Bruce M Foxman; Christine M Thomas

doi:10.1021/ja2071847

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Activation of CO2 by a heterobimetallic Zr/Co complex

Journal article

Peer reviewed

Activation of CO2 by a heterobimetallic Zr/Co complex

Jeremy P Krogman, Bruce M Foxman and Christine M Thomas

Journal of the American Chemical Society, Vol.133(37), pp.14582-14585

09/21/2011

DOI: https://doi.org/10.1021/ja2071847

PMID: 21875088

Abstract

Redox reactions

Anions

Infrared light

Reactivity

Ligands

At room temperature, the early/late heterobimetallic complex Co((i)Pr(2)PNMes)(3)Zr(THF) has been shown to oxidatively add CO(2), generating (OC)Co((i)Pr(2)PNMes)(2)(μ-O)Zr((i)Pr(2)PNMes). This compound can be further reduced under varying conditions to generate either the Zr oxoanion (THF)(3)Na-O-Zr(MesNP(i)Pr(2))(3)Co(CO) or the Zr carbonate complex (THF)(4)Na(2)(CO(3))-Zr(MesNP(i)Pr(2))(3)Co(CO). Additionally, reactivity of the CO(2)-derived product has been observed with PhSiH(3) to generate the Co-hydride/Zr-siloxide product (OC)(H)Co((i)Pr(2)PNMes)(3)ZrOSiH(2)Ph.

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Title: Activation of CO2 by a heterobimetallic Zr/Co complex
Creators: Jeremy P Krogman - Department of Chemistry, Brandeis University, 415 South Street, MS 015, Waltham, Massachusetts 02454, USA
Bruce M Foxman
Christine M Thomas
Publication Details: Journal of the American Chemical Society, Vol.133(37), pp.14582-14585
Identifiers: 9923989576501921
Academic Unit: Department of Chemistry
Language: English
Resource Type: Journal article

Activation of CO2 by a heterobimetallic Zr/Co complex

Abstract

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