Abstract
Alkenes and Glycals react with Mn(OAc3)·2H2O and NaN3 in 9:1 acetonitrile-trifluoroacetic acid to give 1,2-diazides in >80% yield. Allylic azides are formed by slow addition of NaN3 to a mixture of alkene, Mn(OAc)3·2H2O and Cu(OAc)2.
- Title
- An Improved Procedure for the Conversion of Alkenes and Glycals to 1,2-Diazides Using Mn(OAc)3·2H2O in Acetonitrile Containing Trifluoroacetic Acid
- Creators
- Barry B Snider - Department of Chemistry , Brandeis UniversityHong Lin - Department of Chemistry , Brandeis University
- Publication Details
- Synthetic communications, Vol.28(10), pp.1913-1922
- Publisher
- Taylor & Francis Group
- Identifiers
- 9924012922001921
- Copyright
- © 1998 Francis & Taylor
- Academic Unit
- Department of Chemistry
- Language
- English
- Resource Type
- Journal article