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Asymmetric carbon-carbon bond formation using optically active (.eta.-C5H5)Fe(CO)2-vinyl ether complexes. Asymmetric control at two adjacent carbon centers
Journal article   Peer reviewed

Asymmetric carbon-carbon bond formation using optically active (.eta.-C5H5)Fe(CO)2-vinyl ether complexes. Asymmetric control at two adjacent carbon centers

Myron Rosenblum, Mark M Turnbull and Bruce M Foxman
Organometallics, Vol.5(5), pp.1062-1063
05/01/1986
DOI: https://doi.org/10.1021/om00136a042

Abstract

The dlhydrodioxln-Fp complex2b(Fp=( -C5H5)Fe(CO)2) adds a broad range of nucleophiles to give optically active adducts 4 in which nucleophile and Fp group are diaxial.These may be converted to optically active Fp (?j2-vinylether) or Fp (r?2-alkene)cations of defined absolute configuration.

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