Catalytic Conversion of Biomass‐Derived Carbohydrates into γ‐Valerolactone without Using an External H2 Supply

Li Deng; Jiang Li; Da‐Ming Lai; Yao Fu; Qing‐Xiang Guo

doi:10.1002/anie.200902281

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Catalytic Conversion of Biomass‐Derived Carbohydrates into γ‐Valerolactone without Using an External H2 Supply

Journal article

Peer reviewed

Catalytic Conversion of Biomass‐Derived Carbohydrates into γ‐Valerolactone without Using an External H2 Supply

Li Deng, Jiang Li, Da‐Ming Lai, Yao Fu and Qing‐Xiang Guo

Angewandte Chemie (International ed.), Vol.48(35), pp.6529-6532

08/17/2009

DOI: https://doi.org/10.1002/anie.200902281

PMID: 19630045

Abstract

formic acid

γ‐valerolactone

sustainable chemistry

levulinic acid

Simplified procedure: A new catalytic route was developed for the conversion of biomass carbohydrates into γ‐valerolactone (GVL) without using an external H2 supply. A model experiment with glucose provided γ‐valerolactone in 48 % yield. An interesting positive effect of CO2 on the Ru‐catalyzed hydrogenation was also observed. py=pyridine.

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Title: Catalytic Conversion of Biomass‐Derived Carbohydrates into γ‐Valerolactone without Using an External H2 Supply
Creators: Li Deng
Jiang Li
Da‐Ming Lai
Yao Fu
Qing‐Xiang Guo
Publication Details: Angewandte Chemie (International ed.), Vol.48(35), pp.6529-6532
Publisher: WILEY‐VCH Verlag; Weinheim
Number of pages: 4
Grant note: 973 program (2007CB210205) NSFC‐Guangdong Joint Fund (U0834005) KIPCAS (KGCX2‐YW‐3306) EYSFAP (08040106829)
Identifiers: 9923972942801921
Academic Unit: Department of Chemistry
Language: English
Resource Type: Journal article

Catalytic Conversion of Biomass‐Derived Carbohydrates into γ‐Valerolactone without Using an External H2 Supply

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