Abstract
The chemical structure of two insoluble tricyclic organic molecules made from the same precursor through different reported synthesis routes and forming promising electrode materials is compared by advanced solid-state
C,
N,
C{
H},
N{
H}, and
N-
N nuclear magnetic resonance (NMR). One synthesis resulted in TAPT, tetraamino-phenazine-1,4,6,9-tetrone, while several prominent publications identified the product of the other procedure as TAQ, with fewer lithium binding sites due to hydrogen atoms bonded to two nitrogen atoms, which also make the central ring antiaromatic. Peak positions in the
C and
N NMR spectra of TAPT and two "TAQ" materials, including
N
-"TAQ", are similar and agree with chemical-shift predictions for TAPT. Differences in line broadening arise from different concentrations of unpaired electrons, confirmed by pronounced differences in spin-lattice relaxation times. Slow
N{
H} and long-range
C{
H} dipolar dephasing proves that like TAPT, "TAQ" does not contain central N-H groups. The aromatic pyrazine ring in TAPT and "TAQ" is confirmed by the 309 ppm chemical shift of the nonprotonated nitrogen atom. Moderate splittings of the
NH
and
C-NH
NMR signals are shown to be due to symmetry-lowering differences in hydrogen bonding. Mass spectra of TAPT and "TAQ" exhibit matching peaks. Quantum-chemical analyses show that formation of TAQ with its antiaromatic central ring is not thermodynamically favorable and that it would spontaneously tautomerize into a reduced form of TAPT. In conclusion, both TAPT and "TAQ" are tetraamino-phenazine-1,4,6,9-tetrone, and published studies of the properties of "TAQ" are therefore duplicative.