Abstract
Intramolecular amination of organoboronates occurs with a 1,2-metalate shift of an aminoboron “ate” complex to form azetidines, pyrrolidines, and piperidines. Bis(boronates) undergo site-selective amination to form boronate-containing azacycles. Enantiomerically enriched azacycles are formed with high stereospecificity.