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Copper(II)-catalyzed trifluoromethylation of N-aryl imines
Journal article   Peer reviewed

Copper(II)-catalyzed trifluoromethylation of N-aryl imines

Yong-Qiang Zhang, Ji-Dan Liu and Hao Xu
Organic & biomolecular chemistry, Vol.11(37), pp.6242-6245
10/07/2013
PMID: 23942911

Abstract

Molecular Structure Copper - chemistry Catalysis Methylation Fluorine - chemistry Imines - chemistry
Methods for imine trifluoromethylation are of great importance because amines with trifluoromethylated stereogenic centers are useful building blocks for synthetic chemistry and drug discovery. Herein, we describe a new copper(II)-catalyzed imine trifluoromethylation method without the use of Lewis base activators, presumably through cooperative activation.

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