Crystal and Molecular Structure of the bis-Ethyl Urethane of 5,7-Dodecadiyn-1,12,diol (ETCD)

Xiaoyu Wang; Daniel J Sandman; Volker Enkelmann; Chun-Hsing Chen; Bruce M Foxman

doi:10.1080/10601320802380109

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Journal article

Crystal and Molecular Structure of the bis-Ethyl Urethane of 5,7-Dodecadiyn-1,12,diol (ETCD)

Xiaoyu Wang, Daniel J Sandman, Volker Enkelmann, Chun-Hsing Chen and Bruce M Foxman

Journal of macromolecular science. Part A, Pure and applied chemistry, Vol.45(11), pp.914-916

09/26/2008

DOI: https://doi.org/10.1080/10601320802380109

Abstract

crystal structure

Diacetylene monomer

thermochromic polydiacetylenes

Grown from ethyl acetate solution, the bis-ethylurethane of 5,7-dodecadiyn-1,12-diol is a monoclinic crystal, a = 16.9740(16), b = 4.9770(5), c = 11.0874(11) Å; β = 101.869(6)°; Z = 2; V = 916.63(16) Å3. The crystal structure contains two N─H…O hydrogen bonds per molecule and has nearly ideal parameters (d = 4.977 Å, ϕ = 45.8°, R = 3.477 Å) for solid-state polymerization.

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Title: Crystal and Molecular Structure of the bis-Ethyl Urethane of 5,7-Dodecadiyn-1,12,diol (ETCD)
Creators: Xiaoyu Wang - Center for Advanced Materials, Department of Chemistry , University of Massachusetts Lowell
Daniel J Sandman - Center for Advanced Materials, Department of Chemistry , University of Massachusetts Lowell
Volker Enkelmann - Max-Planck-Institut für Polymerforschung
Chun-Hsing Chen - Department of Chemistry , Brandeis University
Bruce M Foxman - Department of Chemistry , Brandeis University
Publication Details: Journal of macromolecular science. Part A, Pure and applied chemistry, Vol.45(11), pp.914-916
Publisher: Taylor & Francis Group
Identifiers: 9923989477401921
Academic Unit: Department of Chemistry
Language: English
Resource Type: Journal article

Crystal and Molecular Structure of the bis-Ethyl Urethane of 5,7-Dodecadiyn-1,12,diol (ETCD)

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