Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center

Remle Çelenligil-Çetin; Lori A Watson; Chengyun Guo; Bruce M Foxman; Oleg V Ozerov

doi:10.1021/om049061m

Back

Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center

Journal article

Peer reviewed

Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center

Remle Çelenligil-Çetin, Lori A Watson, Chengyun Guo, Bruce M Foxman and Oleg V Ozerov

Organometallics, Vol.24(2), pp.186-189

01/01/2005

DOI: https://doi.org/10.1021/om049061m

Abstract

Alcohols

Mathematical methods

Organic reactions

Ketones

Ligands

A Ru center ligated by a pincer bis(o-phosphinoaryl)amine (PNP) ligand in (PNP)RuH(H2) is sufficiently electron rich to break C−O and C−C bonds, resulting in the ultimate decarbonylation of hydrocarbonate and acetone, respectively, to give (PNP)RuH(CO). The decarbonylation of acetone is accompanied by hydrogenolysis of the C−C bonds to produce methane.

Metrics

20 Record Views

See more details

Details

Title: Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center
Creators: Remle Çelenligil-Çetin - Departments of Chemistry, Brandeis University, MS015, 415 South Street, Waltham, Massachusetts 02454, and Earlham College, 801 National West Road, Richmond, Indiana 47374
Lori A Watson - Departments of Chemistry, Brandeis University, MS015, 415 South Street, Waltham, Massachusetts 02454, and Earlham College, 801 National West Road, Richmond, Indiana 47374
Chengyun Guo - Departments of Chemistry, Brandeis University, MS015, 415 South Street, Waltham, Massachusetts 02454, and Earlham College, 801 National West Road, Richmond, Indiana 47374
Bruce M Foxman - Departments of Chemistry, Brandeis University, MS015, 415 South Street, Waltham, Massachusetts 02454, and Earlham College, 801 National West Road, Richmond, Indiana 47374
Oleg V Ozerov - Departments of Chemistry, Brandeis University, MS015, 415 South Street, Waltham, Massachusetts 02454, and Earlham College, 801 National West Road, Richmond, Indiana 47374
Publication Details: Organometallics, Vol.24(2), pp.186-189
Identifiers: 9923989470301921
Academic Unit: Department of Chemistry
Language: English
Resource Type: Journal article

Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center

Abstract

Metrics

Details

Brandeis University Social media