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Enantioselective Friedel-Crafts reaction of indoles with carbonyl compounds catalyzed by bifunctional cinchona alkaloids
Journal article   Peer reviewed

Enantioselective Friedel-Crafts reaction of indoles with carbonyl compounds catalyzed by bifunctional cinchona alkaloids

Hongming Li, Yong-Qiang Wang and Li Deng
Organic letters, Vol.8(18), pp.4063-4065
08/01/2006
PMID: 16928074

Abstract

Catalysis Indoles - chemistry Cinchona Alkaloids - chemistry Molecular Biology
In this communication, we report an efficient asymmetric Friedel-Crafts reaction that, unprecedently, is applicable to a wide range of both indoles and carbonyls. The use of a readily accessible catalyst in combination with a high enantioselectivity that is insensitive to reaction concentration, temperature, air, and moisture should allow this reaction to provide useful enantioselective access to new chiral indole derivatives.

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