Facile oxidative addition of N-C and N-H bonds to monovalent rhodium and iridium

Oleg V OZEROV; CHENGYUN GUO; Vyacheslav A PAPKOV; Bruce M FOXMAN

doi:10.1021/ja049659l

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Facile oxidative addition of N-C and N-H bonds to monovalent rhodium and iridium

Journal article

Peer reviewed

Facile oxidative addition of N-C and N-H bonds to monovalent rhodium and iridium

Oleg V OZEROV, CHENGYUN GUO, Vyacheslav A PAPKOV and Bruce M FOXMAN

Journal of the American Chemical Society, Vol.126(15), pp.4792-4793

04/01/2004

DOI: https://doi.org/10.1021/ja049659l

PMID: 15080679

Abstract

Chemistry

Kinetics and mechanisms

Reactivity and mechanisms

Exact sciences and technology

Transition metals

Oxidative addition

Organic reactions

Molecules

Organic Chemistry

Ligands

An investigation of room-temperature oxidative addition of N−C and N−H bonds to RhI and IrI in solution and in the solid state is presented. The rigid, product-adapted framework of the pincer bis(ortho-phosphinoaryl)amine (PNP) ligand may contribute to the ease of the N−C and N−H cleavage. The migration of Me from N of the coordinated amine moiety to Rh proceeds with near-zero entropy of activation in solution. In the solid state, this transformation is a crystal-to-crystal reaction, transforming only one of the two independent molecules of (PN(Me)P)RhCl into (PNP)Rh(Me)Cl.

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Title: Facile oxidative addition of N-C and N-H bonds to monovalent rhodium and iridium
Creators: Oleg V OZEROV - Department of Chemistry, Brandeis University, MS015, 415 South Street, Waltham Massachusetts 02454, United States
CHENGYUN GUO - Department of Chemistry, Brandeis University, MS015, 415 South Street, Waltham Massachusetts 02454, United States
Vyacheslav A PAPKOV - Department of Chemistry, Brandeis University, MS015, 415 South Street, Waltham Massachusetts 02454, United States
Bruce M FOXMAN - Department of Chemistry, Brandeis University, MS015, 415 South Street, Waltham Massachusetts 02454, United States
Publication Details: Journal of the American Chemical Society, Vol.126(15), pp.4792-4793
Publisher: American Chemical Society
Identifiers: 9923989566801921
Academic Unit: Department of Chemistry
Language: English
Resource Type: Journal article

Facile oxidative addition of N-C and N-H bonds to monovalent rhodium and iridium

Abstract

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