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Fluctuation-dissipation ratios in the dynamics of self-assembly
Journal article

Fluctuation-dissipation ratios in the dynamics of self-assembly

Robert L Jack, Michael F Hagan and David Chandler
Physical review. E, Statistical, nonlinear, and soft matter physics, Vol.76(2 Pt 1), pp.021119-021119
08/2007
PMID: 17930018

Abstract

Models, Theoretical Temperature Capsid - chemistry Time Factors Viruses - chemistry Molecular Conformation Kinetics Models, Statistical Biophysics - methods Diffusion Chemistry, Physical - methods Biophysics Chemical Kinetics Thermodynamics Virology
We consider two seemingly very different self-assembly processes: formation of viral capsids and crystallization of sticky disks. At low temperatures, assembly is ineffective, since there are many metastable disordered states, which are a source of kinetic frustration. We use fluctuation-dissipation ratios to extract information about the degree of this frustration. We show that our analysis is a useful indicator of the long-term fate of the system, based on the early stages of assembly.
url
https://doi.org/10.1103/PhysRevE.76.021119View
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