Abstract
Oxidative free-radical cyclization of 4-(3-hexcnyl)-1,3-cyclohexanedione 8 affords 85% of a mixture of 7 and 29. Short sequences were developed to convert this mixture to 2, a late intermediate in Taschner's synthesis of upial.
- Title
- Formal synthesis of (±)-upial. Oxidative free-radical cyclization of unsaturated 1,3-cyclohexanediones
- Creators
- Barry B Snider (Author)Steven V O'Neil (Author)
- Publication Details
- Tetrahedron, Vol.51(47), pp.12983-12994
- Publisher
- Elsevier Ltd
- Identifiers
- 9924012822201921
- Copyright
- © 1995 Published by Elsevier Ltd.
- Academic Unit
- Department of Chemistry
- Language
- English
- Resource Type
- Journal article