Abstract
The (PNP)PdOTf complex is a suitable synthetic equivalent of the [(PNP)Pd](+) fragment in reactions with various HX substrates. The [(PNP)Pd](+) fragment either simply binds HX molecules as L-type ligands (X = NH(2), PCy(2), imidazolyl) or heterolytically splits the H-X bond to produce [(PN(H)P)Pd-X](+) (X = H, CCR, SR). DFT calculations analyze the relative energetics of the two outcomes and agree with the experimental data. Calculations also allow to assess the unobserved Pd(IV) isomer [(PNP)Pd(H)(2)](+) and validate its unfavourability with respect to the Pd(II) isomer [(PN(H)P)PdH](+).