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Increased stability of phosphite ozonides derived from 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo[2.2.2]octane
Journal article   Peer reviewed

Increased stability of phosphite ozonides derived from 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo[2.2.2]octane

Socorro M Ramos, Jeffrey C Owrutsky and Philip M Keehn
Tetrahedron letters, Vol.26(48), pp.5895-5898
1985

Abstract

Substituent changes at the hydroxyl group in the title compound affect the stability of the corresponding phosphite ozonides generated at the remote phosphorous atom. The benzoyl derivative was found to have a half-life > 100 minutes at 180°C and is at least 10 times more stable at that temperature than 1-phospha-2,8,9-trioxaadamantane ozonide.

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