Chemical Reactions Chemical Synthesis Organic Chemistry
Vinylketenes prepared from geranoyl and farnesoyl chloride by treatment with triethylamine react to give bicyclo[ 3.1.1 ] heptanones which can be converted to β-pinene and the β-bergamotenes by Wolff-Kishner reduction.
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Title
Intramolecular [2 + 2] cycloadditions of ketenes. 2. Synthesis of chrysanthenone, .beta.-pinene, .beta.-cis-bergamotene, and .beta.-trans-bergamotene
Creators
Yashwant S Kulkarni (Author)
Barry B Snider (Author)
Publication Details
Journal of organic chemistry, Vol.50(15), pp.2809-2810