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Nickel-catalyzed carbometallation of functionalized silylalkynes by grignard reagents
Journal article   Peer reviewed

Nickel-catalyzed carbometallation of functionalized silylalkynes by grignard reagents

Barry B Snider, Robin S.E Conn and Michael Karras
Tetrahedron letters, Vol.20(19), pp.1679-1682
1979

Abstract

Chemical Synthesis
Syntheses of vinylsilanes by the nickel catalyzed addition of methyl-magnesium bromide to functionalized silylalkynes are described. Simple syntheses of geraniol and farnesol are reported.

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