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Oligomerization Oscillations of l-Lactic Acid in Solution
Journal article

Oligomerization Oscillations of l-Lactic Acid in Solution

Mieczysław Sajewicz, Miloš Dolnik, Dorota Kronenbach, Monika Gontarska, Teresa Kowalska and Irving R Epstein
The Journal of Physical Chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, Vol.115(50), pp.14331-14339
12/22/2011
PMID: 22054006

Abstract

A: Kinetics, Spectroscopy High-performance liquid chromatography Oligomerization Ethanol Oscillation Chromatography Physical Chemistry
We employ high-performance liquid chromatography with diode array, evaporative light scattering, and mass spectrometric detection to monitor the oligomerization of l-lactic acid in pure acetonitrile and in 70% aqueous ethanol. The production of higher oligomers appears to proceed in an oscillatory fashion. A model is presented that involves the formation of aggregates (micelles), which catalyze the oligomerization.

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