Reaction of TaCl2(Me2PC2H4PMe2)2 with Na[H2Al(OC2H4OMe)2] affords [Ta{H2Al(OC2H4OMe)2}(Me2PC2H4PMe2)2]2, a co-ordinatively unsaturated complex based on an approximately square-pyramidal P4Ta–µ-H2–Al group.
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Title
Preparation and molecular structure of [Ta{H2Al(OC2H4OMe)2}(Me2PC2H4PMe2)2]2, a co-ordinatively unsaturated aluminohydride adduct of tantalum(I)
Creators
Timothy J McNeese
Stan S Wreford
Bruce M Foxman
Publication Details
Journal of the Chemical Society, Chemical Communications, (12), pp.500-501