Abstract
Not too close for comfort: Practical chiral organocatalysts like that shown promote Michael addition reactions of a wide range of trisubstituted carbon nucleophiles to various nitroalkenes, often with nearly perfect stereoselectivity (>99 % ee and >98:2 d.r.). In one step adjacent carbon‐ or heteroatom‐substituted quaternary and tertiary stereocenters are generated from readily available starting materials.