Chemical Reactions Radiosources, Infrared, X-ray, Gamma Ray Irradiation
Irradiation (60Co γ-rays) of crystalline bis(trans-but-2-enoato)calcium induces a unique solid-state cyclodimerization reaction; the product, cis,trans-nepetic acid, is one of four possible diastereomers.
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Stereospecific γ-ray-induced dimerization of crystalline bis(trans-but-2-enoato)calcium