Structure and solid state reaction of tris(propynoato)scandium(III), an unusual coordination polymer

J. S BRODKIN; B. M FOXMAN

doi:10.1039/C39910001073

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Journal article

Structure and solid state reaction of tris(propynoato)scandium(III), an unusual coordination polymer

J. S BRODKIN and B. M FOXMAN

Journal of the Chemical Society. Chemical communications, (16), pp.1073-1075

1991

DOI: https://doi.org/10.1039/C39910001073

Abstract

Structure of solids and liquids; crystallography

Inorganic compounds

Structure of specific crystalline solids

Exact sciences and technology

Condensed matter: structure, mechanical and thermal properties

Physics

Irradiation (60Co γ-rays) of the novel, cubic three-dimensional coordination polymer, tris(propynoato)scandium(III), induces a solid-state polymerization reaction; analysis of the structure indicates that the criterion of parallelism is not a necessary requirement for the reactivity of monoacetylenes in solids.

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Title: Structure and solid state reaction of tris(propynoato)scandium(III), an unusual coordination polymer
Creators: J. S BRODKIN - Brandeis univ., dep. chemistry, Waltham MA 02254-9110, United States
B. M FOXMAN - Brandeis univ., dep. chemistry, Waltham MA 02254-9110, United States
Publication Details: Journal of the Chemical Society. Chemical communications, (16), pp.1073-1075
Publisher: Royal Society of Chemistry
Identifiers: 9923989574801921
Academic Unit: Department of Chemistry
Language: English
Resource Type: Journal article

Structure and solid state reaction of tris(propynoato)scandium(III), an unusual coordination polymer

Abstract

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