Logo image
Home Academic units
Sign in
Systematic design of chemical oscillators. 12. Bistability in the oxidation of iron(II) by nitric acid
Journal article

Systematic design of chemical oscillators. 12. Bistability in the oxidation of iron(II) by nitric acid

Miklos Orban and Irving R Epstein
Journal of the American Chemical Society, Vol.104(22), pp.5918-5922
11/01/1982

Abstract

Oxidation Iron(II) Nitric Acid1
The autocatalytic reaction between ferrous ion and nitric acid has been studied at 25 °C in a continuous flow stirred tank reactor. The system exhibits bistability as a function of flow rate for a wide range of Fe(II) and HN03 input fluxes. The results obtained are in good agreement with a seven-step mechanism proposed earlier to account for the batch ferrous-nitric acid clock reaction. The possibility of constructing a chemical oscillator based on this system is discussed briefly.

Metrics

21 Record Views

Details