Systematic design of chemical oscillators. 47. Kinetics and mechanism of the oxidation of hexacyanoferrate(II) by bromate

Gyula Rabai; Irving R Epstein

doi:10.1021/ic00303a024

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Systematic design of chemical oscillators. 47. Kinetics and mechanism of the oxidation of hexacyanoferrate(II) by bromate

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Systematic design of chemical oscillators. 47. Kinetics and mechanism of the oxidation of hexacyanoferrate(II) by bromate

Gyula Rabai and Irving R Epstein

Inorganic chemistry, Vol.28(4), pp.732-736

02/01/1989

DOI: https://doi.org/10.1021/ic00303a024

Abstract

Chemical Kinetics

Computer Simulation or Modeling

The kinetics of the reaction between Fe(CN)64~ and Br03" have been studied spectrophotometrically in the pH range 3.6-5.8. A mechanism is proposed in which the active species is Fe(CN)5H203~. The mechanism accounts for the observed complex kinetics, including the dependence on reactant concentrations and the effects of light. Numerical simulations with this mechanism give excellent agreement with the experimental results

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Title: Systematic design of chemical oscillators. 47. Kinetics and mechanism of the oxidation of hexacyanoferrate(II) by bromate
Creators: Gyula Rabai (Author)
Irving R Epstein (Author) - Brandeis University, Department of Chemistry
Publication Details: Inorganic chemistry, Vol.28(4), pp.732-736
Publisher: American Chemical Society
Identifiers: 9924131325401921
Academic Unit: Benjamin and Mae Volen National Center for Complex Systems; Department of Chemistry; Interdepartmental Program in Neuroscience
Language: English
Resource Type: Journal article

Systematic design of chemical oscillators. 47. Kinetics and mechanism of the oxidation of hexacyanoferrate(II) by bromate

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