Triflyloxy-substituted carboranes as useful weakly coordinating anions

Loren P Press; Billy J McCulloch; Weixing Gu; Chun-Hsing Chen; Bruce M Foxman; Oleg V Ozerov

doi:10.1039/C5CC05047B

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Journal article

Triflyloxy-substituted carboranes as useful weakly coordinating anions

Loren P Press, Billy J McCulloch, Weixing Gu, Chun-Hsing Chen, Bruce M Foxman and Oleg V Ozerov

Chemical communications (Cambridge, England), Vol.51(74), pp.14034-14037

09/01/2015

DOI: https://doi.org/10.1039/C5CC05047B

PMID: 26251850

Abstract

New carborane anions carrying one or three triflyloxy substituents are described. The mono-triflyloxy substituted carborane can be halogenated to give pentabromo and decachloro derivatives with preservation of the B–OTf linkage. The use of [HCB11Cl10OTf]−as a weakly coordinating anion is demonstrated.

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Title: Triflyloxy-substituted carboranes as useful weakly coordinating anions
Creators: Loren P Press - Department of Chemistry, Texas A&M University, College Station, USA
Billy J McCulloch - Department of Chemistry, Texas A&M University, College Station, USA
Weixing Gu - Department of Chemistry, Texas A&M University, College Station, USA, Department of Chemistry
Chun-Hsing Chen - Department of Chemistry, Brandeis University, Waltham, USA
Bruce M Foxman - Department of Chemistry, Brandeis University, Waltham, USA
Oleg V Ozerov - Department of Chemistry, Brandeis University, Waltham, USA
Publication Details: Chemical communications (Cambridge, England), Vol.51(74), pp.14034-14037
Identifiers: 9923989578701921
Academic Unit: Department of Chemistry
Language: English
Resource Type: Journal article

Triflyloxy-substituted carboranes as useful weakly coordinating anions

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